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uŽtŽ–¼F Prof. Junpo He Š @ ‘®F Dept. of Macromolecular Science, Fudan University, China
‘è@@–ÚF Synthesis of Dendrimer-like Polymers by Divergent "End-grafting"
Approach through Anionic Polymerization
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We have developed a divergent gend-graftingh approach to synthesize
dendrimer-like polymers through anionic attack of the periphery epoxy
groups of the preceding generations. The method is easy to
achieve high chain densities as well as high multiplicity of periphery
chain ends.  The approach can also be used in the synthesis of
dendronized polymer brushes.  The inner structures of the dendrimer-
like polymers and the dendronized polymer brushes will be discussed.